u can put any colour on once you have a high temp paint as a base, as you can use it as a primer for another colour, i had the same set up painted my TB peugeot met red, and inlet yellow lol,
steps you need
high temperature paint, = spray, use this for a final colour or as a base,
colour of your choice, = metallics or non metallic, in spray
high temp clear coat for over the top, in spray
for the head you just need to spray it silver again high temp paint then high temp clear coat over the top, i intend to put 3-4 layers of paint on as drys like a matt then clear coat it about 3-4 times, and that was on a XE bottom end and when i removed it, it never flaked